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Manufacturer supply 2-METHYL-2-PROPENE-1,1-DIOL DIACETATE 10476-95-6 with sufficient stock and high standard
- Molecular Formula:C8H12 O4
- Molecular Weight:172.181
- Vapor Pressure:760 mm Hg ( 191 °C)
- Melting Point:?15 °C(lit.)
- Refractive Index:n20/D 1.424(lit.)
- Boiling Point:191 °C at 760 mmHg
- Flash Point:83.3 °C
- PSA：52.60000
- Density:1.057 g/cm3
- LogP:1.01480
2-METHYL-2-PROPENE-1,1-DIOL DIACETATE(Cas 10476-95-6) Usage
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Reactivity Profile |
2-METHYL-2-PROPENE-1,1-DIOL DIACETATE reacts exothermically with acids. Strong oxidizing acids may cause a reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated with basic solutions. Flammable hydrogen may be generated by mixing with alkali metals and hydrides. Reacts readily with mercaptans. Acidic conditions favor breakdown to methacrolein, which is subject to possibly vigorous polymerization. |
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Fire Hazard |
When heated to decomposition, 2-METHYL-2-PROPENE-1,1-DIOL DIACETATE emits acrid smoke and irritating fumes. |
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Safety Profile |
Poison by inhalation, skin contactand intraperitoneal routes. Moderately toxic by ingestion. When heated to decomposition it emitsacrid smoke and irritating fumes. |
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General Description |
A liquid. Density 1.04 g / cm3; highly toxic. |
InChI:InChI=1/C8H12O4/c1-5(2)8(11-6(3)9)12-7(4)10/h8H,1H2,2-4H3
10476-95-6 Relevant articles
Phosphorus Trichloride as Catalyst in the Preparation of 1,1-Diacetates from Aldehydes
Michie, Jacqueline K.,Miller, J. Allen
, p. 824 (1981)
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Solvent free catalytic synthesis of 2-methylallylidene diacetate using cation-exchange resin
Wang, Baohe,Zhang, Haojian,Jing, Xin,Zhu, Jing
, p. 753 - 757 (2010)
2-Methylallylidene diacetate (DMA) was s...
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Shono,T. et al.
, p. 3532 - 3536 (1974)
-
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Shirafuji,T. et al.
, p. 4713 - 4714 (1971)
-
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Smith et al.
, p. 5282,5284 (1951)
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Method for preparing anethol propionaldehyde by anisole
-
Paragraph 0050-0052; 0055-0057, (2021/10/27)
The invention relates to the technical f...
An efficient TiCl4-catalysed method for the synthesis of para-substituted aromatic aldehydes
Zhou, Chenfeng,Su, Weike
, p. 555 - 557 (2015/11/27)
An efficient and highly selective synthe...
2-METHYL-3-(3,4-METHYLENEDIOXYPHENYL)PROPANAL, AND METHOD FOR PRODUCTION THEREOF
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Page/Page column 13-14, (2009/12/05)
Disclosed are: (1) a method for producin...
10476-95-6 Process route
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78-85-3,25120-30-3
2-methylpropenal
-
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108-24-7
acetic anhydride
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-
10476-95-6
methallylidene diacetate
| Conditions | Yield |
|---|---|
|
phosphorus trichloride;
at 20 ℃;
for 10h;
|
88% |
|
With
lithium tetrafluoroborate;
In
diethyl ether;
at 20 ℃;
for 22h;
|
87% |
|
With
boron trifluoride diethyl etherate;
at -10 ℃;
for 3.3h;
|
85% |
|
With
sulfuric acid;
|
|
|
With
tin(ll) chloride;
dann bei 20-25gradC;
|
|
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With
boric acid; oxalic acid;
|
|
|
With
phosphoric acid;
at 150 - 250 ℃;
|
|
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With
zinc(II) chloride;
at -3 - 0 ℃;
|
|
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With
zinc(II) chloride;
|
|
|
With
boron trifluoride diethyl etherate;
at 0 - 20 ℃;
Product distribution / selectivity;
Inert atmosphere;
|
|
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With
D072 mesoporous strong acidic cation-exchange resin;
at -15.16 ℃;
Temperature;
Kinetics;
Equilibrium constant;
Inert atmosphere;
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|
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With
tin(ll) chloride;
dann bei 20-25gradC;
|
|
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With
sulfuric acid;
|
|
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With
boric acid; oxalic acid;
|
|
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With
boron trifluoride diethyl etherate;
at 0 - 20 ℃;
for 2h;
Temperature;
Inert atmosphere;
|
-
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64-19-7,77671-22-8
acetic acid
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-
14478-14-9
1-acetyloxy-2-methylpropene
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-
10476-95-6
methallylidene diacetate
| Conditions | Yield |
|---|---|
|
(electrochemical oxidation);
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10476-95-6 Upstream products
-
78-85-3
2-methylpropenal
-
108-24-7
acetic anhydride
-
3664-56-0
1,3,3-trimethylcyclopropene
-
2570-63-0
thallium(III) acetate
10476-95-6 Downstream products
-
20668-26-2
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-
97041-62-8
6-chloro-3-methylquinoline
-
2801-32-3
3-methyl-8-nitroquinoline
-
20668-28-4
2,7-dimethylquinoline
