Current location:Home > Pharmaceutical
Product
Quality products?make an important contribution to long-term revenue and profitability. Cyclohexanemethanol Good Manufacturer supply High Quality 100-49-2
1.What is the Cyclohexanemethanol ?
Cyclohexanemethanol (Cyclohexyl methanol) can be used as a starting material for the synthesis of cyclohexanecarboxaldehyde, cyclohexanecarboxylic acid, cyclohexanone, and 1,4-cyclohexadione by photocatalytic oxidation (PCO) using titanium dioxide nanoparticles as a catalyst.
-
-
121-91-5
isophthalic acid
-
-
3971-31-1
cyclohexane-1,3-dicarboxylic acid
-
-
13293-59-9
3-methylcyclohexanecarboxylic acid
-
-
100-49-2
cyclohexylmethyl alcohol
-
-
98-89-5
Cyclohexanecarboxylic acid
| Conditions | Yield |
|---|---|
|
With
5% active carbon-supported ruthenium; hydrogen;
In
1,4-dioxane;
at 219.84 ℃;
for 12h;
under 51680.2 Torr;
|
-
-
4630-82-4
methyl cyclohexylcarboxylate
-
-
100-49-2
cyclohexylmethyl alcohol
| Conditions | Yield |
|---|---|
|
With
dimethylsulfide borane complex;
In
2-methyltetrahydrofuran;
at 90 ℃;
for 0.333333h;
under 7500.75 Torr;
Inert atmosphere;
Flow reactor;
|
95%
|
|
methyl cyclohexylcarboxylate;
With
3-phenyl-propionaldehyde; diethylaluminum benzenethiolate;
In
hexane; toluene;
at -78 ℃;
for 1.08333h;
Inert atmosphere;
With
diisobutylaluminium hydride;
In
hexane; toluene;
at -78 - 0 ℃;
Inert atmosphere;
With
hydrogenchloride;
In
hexane; water; toluene;
at 0 ℃;
chemoselective reaction;
|
93%
|
|
With
C18H28Br2N4Ru; potassium tert-butylate; hydrogen;
In
1,4-dioxane;
at 105 ℃;
for 8h;
under 22502.3 Torr;
|
93%
|
|
With
sodium tetrahydroborate; sodium methylate;
In
methanol;
at 25 ℃;
for 3h;
Reagent/catalyst;
Inert atmosphere;
|
90%
|
|
With
hydrogen; sodium methylate;
homogeneous ruthenium complex;
In
tetrahydrofuran;
at 100 ℃;
for 2.5h;
under 37503.8 Torr;
|
89%
|
|
With
phenylsilane; dimanganese decacarbonyl;
In
neat (no solvent);
at 100 ℃;
for 24h;
Reagent/catalyst;
Sealed tube;
|
85%
|
|
With
hydrogen; sodium methylate;
dichloro-bis-[2-(diphenylphosphino)ethylamine]ruthenium;
In
tetrahydrofuran;
at 100 ℃;
for 2.5h;
under 37503.8 Torr;
Product distribution / selectivity;
|
82%
|
|
With
hydrogen; sodium methylate;
trans, cis-[RuCl2(1-amino-2-diphenylphosphinoethane-N,P)2]; cis-RuCl2(Ph2P(CH2)2NH2)2;
In
tetrahydrofuran;
at 100 ℃;
for 2.5h;
under 37503.8 Torr;
Conversion of starting material;
|
82%
|
|
With
n-butyllithium; [(1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene)FeCl2];
In
hexane; toluene;
at 100 ℃;
for 20h;
Inert atmosphere;
Schlenk technique;
Glovebox;
Sealed tube;
|
82%
|
|
With
tert-butyl alcohol;
In
tetrahydrofuran;
electrolysis (Mg electrodes, LiClO4);
|
81%
|
|
With
lithium aluminium tetrahydride;
In
diethyl ether;
for 2h;
Ambient temperature;
|
75%
|
|
With
15-crown-5; (1-(2-(2,3-diisopropyl-1-methylguanidino)ethyl)-3-mesityl-1,3-dihydro-2H-imidazol-2-ylidene)copper(I) chloride; hydrogen; sodium t-butanolate;
In
1,4-dioxane;
at 60 ℃;
for 24h;
Inert atmosphere;
|
54%
|
|
With
[iPrPN(H)P]2Fe(H)(CO)(BH4); hydrogen;
In
toluene;
at 115 ℃;
for 24h;
under 12654.8 Torr;
Glovebox;
Sealed tube;
|
50%
|
|
With
zinc(II) tetrahydroborate;
In
1,2-dimethoxyethane;
for 24h;
sonication; or with N,N-dimethylaniline, 14 h;
|
|
|
With
titanium(IV) isopropylate; sodium hydroxide; Triethoxysilane;
Yield given. Multistep reaction;
1.) heating, 16 h, 2.) THF, room temperature;
|
|
|
With
hydrogen; sodium methylate;
[RuCl2(R-BINAP)(S,S-DPEN)];
In
tetrahydrofuran;
at 60 ℃;
for 16h;
under 37503.8 Torr;
Product distribution / selectivity;
|
51 %Chromat.
|
|
With
Tridecane; hydrogen; sodium methylate;
[((R,R)-diphenylethylenediamine)((R)-Binap)dichlororuthenium(II)];
In
tetrahydrofuran;
at 60 ℃;
for 16h;
under 37503.8 Torr;
Autoclave;
|
|
|
With
lithium aluminium tetrahydride;
In
tetrahydrofuran;
at 0 - 45 ℃;
for 1h;
|
|
|
methyl cyclohexylcarboxylate;
With
iron (II) stearate; ethylenediamine;
In
toluene;
at 20 ℃;
for 0.0833333h;
Inert atmosphere;
Schlenk technique;
In
toluene;
at 100 ℃;
for 40h;
Time;
Inert atmosphere;
Schlenk technique;
|
62 %Chromat.
|
|
With
[bis({2‐[bis(propan‐2‐yl)phosphanyl]ethyl})amine](borohydride)(carbonyl)(hydride)iron(II); hydrogen;
In
tetrahydrofuran;
at 120 ℃;
for 19h;
under 37503.8 Torr;
Autoclave;
|
92 %Chromat.
|
|
With
1,1'-methylene-bis(3-benzyl-1H-imidazol-3-ium) diiodide; [ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2; potassium tert-butylate; hydrogen;
In
1,4-dioxane;
at 100 ℃;
for 6h;
under 37503.8 Torr;
|
83 %Chromat.
|
|
With
C27H31ClN4ORu; hydrogen; sodium t-butanolate;
In
toluene;
at 105 ℃;
for 20h;
under 4500.45 Torr;
|
6 %Spectr.
|
|
With
tris(triphenylphosphine)ruthenium(II) chloride; 2-diphenyl-1,2-ethylenediamine; potassium tert-butylate; hydrogen;
In
tetrahydrofuran;
at 40 ℃;
for 16h;
Reagent/catalyst;
|
|
|
With
diisobutylaluminium hydride;
In
diethyl ether; toluene;
at -70 - 20 ℃;
|
|
|
With
[{CyPN(H)P}Co(CH2SiMe3)]-BArF4; hydrogen;
In
tetrahydrofuran;
at 120 ℃;
for 20h;
under 41254.1 Torr;
|
26 %Chromat.
|
|
With
dichlorido-bis[(2-diphenylphosphino)ethyl]amine-cobalt(II); hydrogen; sodium methylate;
In
1,4-dioxane;
at 120 ℃;
for 24h;
under 37503.8 Torr;
Autoclave;
|
52 %Chromat.
|
|
With
HN(CH2CH2C3H3N2Mes)2Cl2; potassium tert-butylate; hydrogen; cobalt(II) chloride;
In
tetrahydrofuran;
at 100 ℃;
for 16h;
under 22502.3 Torr;
Autoclave;
Glovebox;
|
80 %Chromat.
|
|
With
potassium tert-butylate; hydrogen;
In
tetrahydrofuran;
at 80 ℃;
for 16h;
under 37503.8 Torr;
Autoclave;
Glovebox;
|
|
|
With
C36H62N2OP2Ru; hydrogen;
In
isopropyl alcohol;
at 25 ℃;
for 16h;
under 22502.3 Torr;
Autoclave;
|
98 %Chromat.
|
|
With
C22H14MnN2O4(1+)*BF4(1-); potassium hydride;
In
tetrahydrofuran;
at 50 ℃;
Inert atmosphere;
Glovebox;
Sealed tube;
|
2.What is the CAS number for Cyclohexanemethanol ?
The CAS number of Cyclohexanemethanol is 100-49-2.
More information of Cyclohexanemethanol 100-49-2 are:
|
CAS?Number |
100-49-2 |
|
Density |
0.913 g/cm3 |
|
Melting Point |
-43oC |
|
Boiling Point |
181.1 °C at 760 mmHg |
|
Flash Point |
71.1 °C |
|
Vapor Pressure |
0.254mmHg at 25°C |
|
Refractive Index |
n20/D 1.465(lit.) |
|
HS CODE |
29061900 |
|
PSA |
20.23000 |
|
LogP |
1.55900 |
|
Pka |
15.17±0.10(Predicted) |
3.What are another words for Cyclohexanemethanol ?
Synonyms?for?Cyclohexanemethanol 100-49-2:(Hydroxymethyl)cyclohexane;Cyclohexanecarbinol;Cyclohexylcarbinol;Cyclohexylmethylalcohol;NSC 5288;
4.What is the molecular formula of Cyclohexanemethanol?
The chemical formula of ?Cyclohexanemethanol is?C7H14O which containing 7 Carbon atoms,14 Hydrogen atoms and 1 Oxygen atoms,and the molecular weight of??Cyclohexanemethanol?is 114.188.
5.What is Cyclohexanemethanol (100-49-2) used for?
Cyclohexanemethanol, also known as Cyclohexyl methanol, is a colorless liquid with versatile applications across various industries. It is a valuable chemical intermediate and serves as a starting material for the synthesis of various compounds, including cyclohexanecarboxaldehyde, cyclohexanecarboxylic acid, cyclohexanone, and 1,4-cyclohexadione through photocatalytic oxidation (PCO) using titanium dioxide nanoparticles as a catalyst.
InChI:InChI=1/C7H14O/c8-6-7-4-2-1-3-5-7/h7-8H,1-6H2
Relevant articles related to Cyclohexanemethanol:
|
Article |
Source |
|
- |
Rathke,Brown , p. 2740 (1967) |
|
Manganese-catalysed transfer hydrogenation of esters |
Oates, Conor L.,Widegren, Magnus B.,Clarke, Matthew L. , p. 8635 - 8638 (2020) |
6.Buy Cyclohexanemethanol with the best price .
Hubei Yuancheng Saichuang Technology Co., Ltd is a quality supplier of Cyclohexanemethanol. Our main goal is customer satisfaction. Contact us to negotiate the best price for your business on Cyclohexanemethanol 100-49-2.
