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Factory Sells Best Quality 1,7-Dioxaspiro[5.5]undecane 180-84-7 with ISO standards
- Molecular Formula: C9H16O2
- Molecular Weight: 156.225
- Appearance/Colour: clear colorless liquid
- Vapor Pressure: 0.645mmHg at 25°C
- Refractive Index: n20/D 1.464(lit.)
- Boiling Point: 193.5°Cat760mmHg
- Flash Point: 63.9°C
- PSA: 18.46000
- Density: 1.02g/cm3
- LogP: 2.08370
1,7-Dioxaspiro[5.5]undecane(Cas 180-84-7) Usage
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Synthesis Reference(s) |
Tetrahedron, 42, p. 4333, 1986 DOI: 10.1016/S0040-4020(01)87660-2Tetrahedron Letters, 26, p. 535, 1985 DOI: 10.1016/S0040-4039(00)61931-7 |
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Biochem/physiol Actions |
Pheromone for Dacus oleae |
InChI:InChI=1/C9H16O2/c1-3-7-10-9(5-1)6-2-4-8-11-9/h1-8H2
180-84-7 Relevant articles
Pherome syntheses - Model reactions for the synthesis of polyether antibiotics
Ireland,Habich
, p. 1418 - 1427 (1981)
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Deshong,P.,Waltermire,R.E.,Ammon,H.L.
, p. 1901 (1988)
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A simple enantioselective synthesis of (R)- and (S)-1,7-dioxaspiro[5.5]undecane via intramolecular asymmetric oxyselenenylation: A new route to optically active spiroketals
Uchiyama, Masahiko,Oka, Masako,Harai, Satohide,Ohta, Akihiro
, p. 1931 - 1934 (2001)
Both enantiomers of 1,7-dioxaspiro[5.5]u...
Compact chiral environment biphenanthrene skeleton chiral phosphoric acid and preparation method and application thereof
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Paragraph 0063-0065, (2022/03/02)
The invention discloses a diphenanthrene...
A new short synthesis of (±)-olean through cross metathesis
Kranidiotis, Nektarios S.,Grammatoglou, Constantinos E.,Gallos, John K.
, p. 1441 - 1444 (2018/08/29)
A new synthesis of (±)-1,7-dioxaspiro[5....
Type II Anion Relay Chemistry: Exploiting Bifunctional Weinreb Amide Linchpins for the One-Pot Synthesis of Differentiated 1,3-Diketones, Pyrans, and Spiroketals
Farrell, Mark,Melillo, Bruno,Smith, Amos B.
supporting information, p. 232 - 235 (2016/01/25)
The design, synthesis, and validation of...
CHIRAL IMIDODIPHOSPHATES AND DERIVATIVES THEREOF
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, (2013/07/25)
The invention relates to chiral imidodip...
180-84-7 Process route
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5694-92-8
4-[2-(4-hydroxybutyl)[1,3]dioxolan-2-yl]butan-1-ol
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180-84-7,90839-15-9,90839-16-0
1,7-dioxaspiro[5.5]undecane
| Conditions | Yield |
|---|---|
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With
toluene-4-sulfonic acid;
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109-99-9,24979-97-3,77392-70-2
tetrahydrofuran
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542-28-9,26354-94-9
3,4,5,6-tetrahydro-2H-pyran-2-one
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180-84-7,90839-15-9,90839-16-0
1,7-dioxaspiro[5.5]undecane
| Conditions | Yield |
|---|---|
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Yield given. Multistep reaction;
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180-84-7 Upstream products
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5694-92-8
4-[2-(4-hydroxybutyl)[1,3]dioxolan-2-yl]butan-1-ol
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109-99-9
tetrahydrofuran
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542-28-9
3,4,5,6-tetrahydro-2H-pyran-2-one
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5851-37-6
4-(phenylthio)butan-1-ol