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1,7-Dioxaspiro[5.5]undecane

  • CAS No.: 180-84-7
  • Purity: 99%
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Factory Sells Best Quality 1,7-Dioxaspiro[5.5]undecane 180-84-7 with ISO standards

  • Molecular Formula: C9H16O2
  • Molecular Weight: 156.225
  • Appearance/Colour: clear colorless liquid 
  • Vapor Pressure: 0.645mmHg at 25°C 
  • Refractive Index: n20/D 1.464(lit.) 
  • Boiling Point: 193.5°Cat760mmHg 
  • Flash Point: 63.9°C 
  • PSA: 18.46000 
  • Density: 1.02g/cm3 
  • LogP: 2.08370 

1,7-Dioxaspiro[5.5]undecane(Cas 180-84-7) Usage

Synthesis Reference(s)

Tetrahedron, 42, p. 4333, 1986 DOI: 10.1016/S0040-4020(01)87660-2Tetrahedron Letters, 26, p. 535, 1985 DOI: 10.1016/S0040-4039(00)61931-7

Biochem/physiol Actions

Pheromone for Dacus oleae

InChI:InChI=1/C9H16O2/c1-3-7-10-9(5-1)6-2-4-8-11-9/h1-8H2

180-84-7 Relevant articles

Pherome syntheses - Model reactions for the synthesis of polyether antibiotics

Ireland,Habich

, p. 1418 - 1427 (1981)

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Deshong,P.,Waltermire,R.E.,Ammon,H.L.

, p. 1901 (1988)

-

A simple enantioselective synthesis of (R)- and (S)-1,7-dioxaspiro[5.5]undecane via intramolecular asymmetric oxyselenenylation: A new route to optically active spiroketals

Uchiyama, Masahiko,Oka, Masako,Harai, Satohide,Ohta, Akihiro

, p. 1931 - 1934 (2001)

Both enantiomers of 1,7-dioxaspiro[5.5]u...

Compact chiral environment biphenanthrene skeleton chiral phosphoric acid and preparation method and application thereof

-

Paragraph 0063-0065, (2022/03/02)

The invention discloses a diphenanthrene...

A new short synthesis of (±)-olean through cross metathesis

Kranidiotis, Nektarios S.,Grammatoglou, Constantinos E.,Gallos, John K.

, p. 1441 - 1444 (2018/08/29)

A new synthesis of (±)-1,7-dioxaspiro[5....

Type II Anion Relay Chemistry: Exploiting Bifunctional Weinreb Amide Linchpins for the One-Pot Synthesis of Differentiated 1,3-Diketones, Pyrans, and Spiroketals

Farrell, Mark,Melillo, Bruno,Smith, Amos B.

supporting information, p. 232 - 235 (2016/01/25)

The design, synthesis, and validation of...

CHIRAL IMIDODIPHOSPHATES AND DERIVATIVES THEREOF

-

, (2013/07/25)

The invention relates to chiral imidodip...

180-84-7 Process route

4-[2-(4-hydroxybutyl)[1,3]dioxolan-2-yl]butan-1-ol
5694-92-8

4-[2-(4-hydroxybutyl)[1,3]dioxolan-2-yl]butan-1-ol

1,7-dioxaspiro[5.5]undecane
180-84-7,90839-15-9,90839-16-0

1,7-dioxaspiro[5.5]undecane

Conditions
Conditions Yield
With toluene-4-sulfonic acid;
tetrahydrofuran
109-99-9,24979-97-3,77392-70-2

tetrahydrofuran

3,4,5,6-tetrahydro-2H-pyran-2-one
542-28-9,26354-94-9

3,4,5,6-tetrahydro-2H-pyran-2-one

1,7-dioxaspiro[5.5]undecane
180-84-7,90839-15-9,90839-16-0

1,7-dioxaspiro[5.5]undecane

Conditions
Conditions Yield
Yield given. Multistep reaction;

180-84-7 Upstream products

  • 5694-92-8
    5694-92-8

    4-[2-(4-hydroxybutyl)[1,3]dioxolan-2-yl]butan-1-ol

  • 109-99-9
    109-99-9

    tetrahydrofuran

  • 542-28-9
    542-28-9

    3,4,5,6-tetrahydro-2H-pyran-2-one

  • 5851-37-6
    5851-37-6

    4-(phenylthio)butan-1-ol

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